Geography
Document Type
Article
Abstract
The biogeochemical seascape of the western Arctic coastal ocean is in rapid transition. Changes in sea ice cover will be accompanied by alterations in sea-air carbon dioxide (CO2) exchange, of which the latter has been difficult to constrain owing to sparse temporal and spatial data sets. Previous assessments of sea-air CO2 flux have targeted specific subregional areas of the western Arctic coastal ocean. Here a holistic approach is taken to determine the net sea-air CO2 flux over this broad region. We compiled and analyzed an extensive data set of nearly 600,000 surface seawater CO2 partial pressure (pCO2) measurements spanning 2003 through 2014. Using space-time colocated, reconstructed atmospheric pCO2 values coupled with the seawater pCO2 data set, monthly climatologies of sea-air pCO2 differences (ΔpCO2) were created on a 0.2°latitude × 0.5°longitude grid. Sea-air CO2 fluxes were computed using the ΔpCO2 grid and gas transfer rates calculated from climatology of wind speed second moments. Fluxes were calculated with and without the presence of sea ice, treating sea ice as an imperfect barrier to gas exchange. This allowed for carbon uptake by the western Arctic coastal ocean to be assessed under existing and reduced sea ice cover conditions, in which carbon uptake increased 30% over the current 10.9 ± 5.7 Tg C (1 Tg = 1012 g) yr-1 of sea ice-adjusted exchange in the region. This assessment extends beyond previous subregional estimates in the region in an all-inclusive manner and points to key unresolved aspects that must be targeted by future research.
Supporting information also available as a supplementary download.
Publication Title
Global Biogeochemical Cycles
Publication Date
2015
Volume
29
Issue
8
First Page
1190
Last Page
1209
ISSN
0886-6236
DOI
10.1002/2015GB005153
Keywords
Arctic, carbon uptake, coastal ocean, high latitude, sea-air CO fluxes 2
Repository Citation
Evans, Wiley; Mathis, Jeremy T.; Cross, Jessica N.; Bates, Nicholas R.; Frey, Karen E.; Else, Brent G.T.; Papkyriakou, Tim N.; Degrandpre, Mike D.; Islam, Fakhrul; Cai, Wei Jun; Chen, Baoshan; Yamamoto-Kawai, Michiyo; Carmack, Eddy; Williams, William J.; and Takahashi, Taro, "Sea-air CO2 exchange in the western Arctic coastal ocean" (2015). Geography. 213.
https://commons.clarku.edu/faculty_geography/213
Copyright
Published source must be acknowledged with citation: Evans, Wiley, et al. "Sea‐air CO2 exchange in the western Arctic coastal ocean." Global Biogeochemical Cycles 29.8 (2015): 1190-1209.